八氯萘
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| 八氯萘 | |
|---|---|
| File:Octachloornaftaleen t.png | |
| 识别 | |
| CAS号 | 2234-13-1 check |
| SMILES |
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| 性质 | |
| 化学式 | C10Cl8 |
| 摩尔质量 | 403.73 g·mol−1 |
| 外观 | 黄色固体 |
| 密度 | 2.0 g·cm−3[1] |
| 熔点 | 197.5—198 °C（470.6—471.1 K） |
| 沸点 | 440 °C（713 K） |
| 溶解性（水） | 难溶 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
八氯萘是一种有机化合物，化学式为C10Cl8。它是难溶于水的黄色固体[1][2]，于2015年作为多氯萘列入斯德哥尔摩公约附录A和附录C中。[3]它可由萘在磺酰氯中在氯化铁的存在下和氯气反应制得[4]；或由萘和氯气在五氯化锑的存在下于150~210 °C反应得到。[5]它和乙硫醇钠在DMF中反应，可以得到八(乙硫基)萘。[6]它在45~50 °C可以被五氟化钒氧化，得到C10Cl8F8和VF4。[7]
参见[编辑]
参考文献[编辑]
- ↑ 1.0 1.1 Octachlornaphthalin. GESTIS-Stoffdatenbank. [2020-03-10].
- ↑ Jeanne Mager Stellman. Encyclopaedia of Occupational Health and Safety. International Labour Organization. 1998: 298. ISBN 978-92-2-109817-1.
- ↑ All POPs listed in the Stockholm Convention. UN environment programme. [2020-01-09]. （原始内容存档于2022-02-09）.
- ↑ I.L. Knunyants; G.G. Yakobson. Syntheses of Fluoroorganic Compounds. Springer Science & Business Media. 6 December 2012: 114. ISBN 978-3-642-70207-5.
- ↑ Houben-Weyl Methods of Organic Chemistry Vol. V/3, 4th Edition: Fluorine and Chlorine Compounds. Georg Thieme Verlag. 14 May 2014: 670. ISBN 978-3-13-179994-4.
- ↑ Mayer, Roland; Decker, Daniel; Kniess, Torsten; Lang, Reinhard. Nucleophilic substitution of octachloronaphthalene with organothiolates. Zeitschrift fuer Chemie, 1990. 30 (11): 404-405. ISSN: 0044-2402.
- ↑ Vadim V. Bardin, Svetlana G. Bardina. Fluorine addition to polychlorinated and polybrominated ethenes and arenes using vanadium pentafluoride. Journal of Fluorine Chemistry. 2004-10, 125 (10): 1411–1414 [2021-01-09]. doi:10.1016/j.jfluchem.2004.01.013. （原始内容存档于2018-06-22） （English）.
- ↑ Brady, John H.; Redhouse, Alan D.; Wakefield, Basil J. Polyhaloaromatic compounds. Part 47. Synthesis and molecular structure of octabromonaphthalene. Journal of Chemical Research, Synopses, 1982. 6. pp 137.
- ↑ N. R. Conley, J. J. Lagowski. Synthesis of Periodonaphthalene, C 10 I 8 : Permercuration and Subsequent Iododemercuration of Naphthalene in a Triiodide Solution. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 2003-01-12, 33 (10): 1741–1745 [2021-01-09]. ISSN 0094-5714. doi:10.1081/SIM-120026544 （English）.