乙酸氯
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| 乙酸氯 | |
|---|---|
| File:Chlorine acetate.png | |
| 别名 | 次氯酸乙酰酯 |
| 识别 | |
| CAS号 | 758-11-2 check |
| PubChem | 12616564 |
| SMILES |
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| 性质 | |
| 化学式 | C2H3ClO2 |
| 摩尔质量 | 94.5 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
乙酸氯是一种化合物，化学式为CH3COOCl，可由氯气的乙酸溶液和干燥的乙酸汞反应得到。[1]它可用于在有机化合物中引入乙酸酯基（CH3C(=O)O-），[2]如和2-氯-4-甲基苯甲醇反应，得到乙酸(2-氯-4-甲基苯基)甲酯[3]；和环己烯反应，得到乙酸-2-氯环己酯[4]。
参考文献[编辑]
- ↑ De la Mare, P. B. D.; Ketley, A. D.; Vernon, C. A. Chlorine acetate as a reagent for electrophilic chlorine substitution. Research (London), 1953. 6: 12-13S. CAN48: 18058.
- ↑ Patrycja Miszczyk, Ilona Turowska-Tyrk, Paweł Kafarski, Ewa Chmielewska. Three-Component Reaction of Benzylamines, Diethyl Phosphite and Triethyl Orthoformate: Dependence of the Reaction Course on the Structural Features of the Substrates and Reaction Conditions. Molecules. 2017-03-11, 22 (3): 450 [2020-04-19]. ISSN 1420-3049. PMC 6155184 可免费查阅. PMID 28287472. doi:10.3390/molecules22030450. （原始内容存档于2020-02-23） （English）.
- ↑ Alemparte-Gallardo, Carlos; Barfoot, Christopher; Barros-Aguirre, David; Cacho-Izquierdo, Monica; Fiandor Roman, Jose Maria; Hennessy, Alan Joseph; Pearson, Neil David; Remuinan-Blanco, Modesto Jesus. Preparation of tricyclic nitrogen containing compounds as antibacterials. 2009. WO 2009141398 A1.
- ↑ P. B. D. de la Mare, Charmian J. O'Connor, M. J. Rosser, M. A. Wilson. Cyclic transition states in cis- and trans-addition of chlorine acetate to olefinic substances. Journal of the Chemical Society D: Chemical Communications. 1970, (12): 731 [2020-04-19]. ISSN 0577-6171. doi:10.1039/c29700000731 （English）.
